Product ID:GRAY, 11453 000196 406
MSDS Date:06/06/1997
FSC:8010
NIIN:00N083590
MSDS Number: CGQZC

RAABE CORP

N92 W14701 ANTHONY AVE
MENOMONEE FALLS, WI 53052-1090
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 414-255-9500

Cage: 0A3L4

RAABE CORPORATION THE PRECISION COLOR COMPANY

1090 MENOMONEE FALLS, WI 53051-1630 US

Telephone: 414-255-9500/800-966-7580

Cage: 0A3L4

1.80%

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 8%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

2.20%

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 16%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 4%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

2.60%

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 35%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM/1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-BUTANONE; (METHYL ETHYL KETONE) (SARA 313) (CERCLA) LEL

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 8%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM/300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 60%

OSHA PEL N/K

ACGIH TLV: N/K

1.40%

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 11%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

3.3460

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO

RTECS: 9999999ZZ

CONT OF METHYL ETHYL KETONE MAY INCR POTENCY OF

RTECS: 9999999ZZ

RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3

RTECS: 9999999ZZ

ARE NOT ATTAINABLE IN WORKPLACE W/THIS MATL. PROD

RTECS: 9999999ZZ

ON ANIMAL STUDIES. RPTD EXPOS TO TOLUENE HAS BEEN

RTECS: 9999999ZZ

HUMAN CONSEQUENCES OF THIS FINDING IS UNCERTAIN.

RTECS: 9999999ZZ

CONSULT APPROP HEALTH PROFESSIONALS CONCERNING

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: LIQ CONT MAY CAUSE SEV
CORNEAL INJURY. SKIN: MAY CAUSE IRRIT. RPTD & PRLNG CONT MAY CAUSE
ALLERGIC DERM. INHAL: HIGH CONCS OF VAPS MAY CAUSE DIZZ, BRTHG
DFCLTY, HDCH/RESP IRRIT. EXTREMELY HIGH CONCS MAY CAUSE DROW,
STAG, CONFUSION, UNCON, COMA/DEATH. INTENTIONAL MISUSE BY
DELIBERATELY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CONCENTRATING & INHALING CONTENTS CAN
BE HARMFUL/FATAL. INGEST: MOD TOX. MAY CAUSE STOM DISCOMFORT, NAUS,
VOMIT, DIARR, & NARCOSIS. CHRONIC: CHRONIC OVEREXP HAS CAUSED THE
FOLLOWING EFTS IN LAB ANIMALS: KIDNEY, EYE, LUNG, LIVER, SPLEEN, &
BRAIN DMG. HAS CAUSED LIVER DMG IN HUMANS. (ING 9)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. GET
MED ATTN IF IRRIT PERSISTS. SKIN: WASH THORO W/SOAP & WATER & SEEK
MED ATTN. REMOVE CONTAM CLTHG. LAUNDER CONTAM CLTHG BEFORE REUSE.
INHAL: MOVE TO FRESH AIR. IF BRTHG STOPS, APPLY ARTF RESP & SEEK
MED ATTN. INGEST: THE DECISION OF WHETHER TO INDUCE VOMIT/NOT MUST
BE MADE BY MD AFTER CAREFUL CONSIDERATION OF ALL MATLS INGESTED.

Flash Point:<-25F,<-32C
Lower Limits:1.30%
Upper Limits:13.10%
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE OR CHEMICAL FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY SHOULD NOT BE USED EXCEPT TO KEEP DOWN VAPS/COOL CLSD
CONTRS TO PVNT BUILD-UP OF PRESS. (SUP DAT)
Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESS. DO NOT USE/STORE
NEAR SOURCES OF HEAT, SPKS/OPEN FLAME. KEEP AWAY FROM ANY SOURCE OF
HEAT SUCH AS SUNLIGHT, HEATERS/STOVES THAT (SUP DAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID HEAT,
SPARKS, FLAMES AND ANYTHING WHICH COULD CAUSE FIRE. VENTILATE AREA
OF SPILL AND ADJACENT LOW LYING AREAS. AVOID BREATHING SOLVENT
VAPORS. REMOVE WITH INERT ABSORBENT MATERIALS AND NON-SPARKING
TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY AREA WITH
VENTILATION SUITABLE FOR STORING MATERIALS SHOWN IN INGREDIENTS
SECTION. KEEP AWAY FROM HEAT, SPARKS AND FLAME.
Other Precautions:STORE IN A COOL PLACE AWAY FROM DIRECT SUNLIGHT OR
ANY SOURCE OF IGNITION. DO NOT STORE AT TEMPERATURES ABOVE 120F.

Respiratory Protection:IF WORKPLACE EXPOSURE LIMITS ARE EXCEEDED FOR
ANY COMPONENT, A NIOSH APPROVED RESPIRATOR SUITABLE FOR COMPONENTS
LISTED IS RECOMMENDED.
Ventilation:SUFFICIENT VENT, IN VOL & PATTERN, SHOULD BE PROVIDED TO
KEEP AIR CONTAM BELOW CURRENT APPLIC OSHA PEL/ACGIH TLV.
Protective Gloves:CHEMICAL RESISTANT PLASTIC OR RUBBER.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE
SHOWER . IMPERVIOUS CLOTHING IS RECOMMENDED FOR PROLONGED/REPEATED
CONT.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING. WASH
HANDS BEFORE EATING OR SMOKING. SMOKE IN DESIGNATED AREAS ONLY.
Supplemental Safety and Health
% VOLAT:41.237(WT). FIRE FIGHT PROC:IF WATER USED, FOG NOZZ PREF. EXPLO
HAZ:COULD CAUSE CONTR TO BURST. DO NOT PUNCTURE/INCIN. DO NOT
CRUSH/PLACE IN GARBAGE COMPACTOR. DO NOT STORE >120F. AEROSOL CONT
RS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. PROD VAPS ARE HVR/AIR
& MAY TRAVEL LONG DIST TO IGNIT SOURCE & FLASH BACK.

Boiling Pt:B.P. Text:>31F,>-1C
Vapor Pres:108.000
Spec Gravity:0.7680
Evaporation Rate & Reference:0.3900 (N-BU AC=1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume:SUPDAT

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID CONTACT WITH HEAT, SPARKS, AND OPEN
FLAME. PRODUCT MAY EXPLODE IF HEATED. KEEP COOL, AVOID EXPOSURE TO
HEAT.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON DIOXIDE, CARBON MONOXIDE, AND UNIDENTIFIED ORGANIC
MATERIALS.

Waste Disposal Methods:PLACE IN CLOSED CONTAINERS. DISPOSE OF PRODUCT
IN ACCORDANCE WITH LOCAL, COUNTY, STATE, AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.